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It will work Both AA and AAA rechargame batteries are 1.2 volts. So if you have 4 of either size you end up with 4.8 volts. So if you add another 1.2 volt battery of either size you will end up with 6 volts. And you can mix 1 AA with 4 AAA, just keep in mind you can only charge AA with AA, and AAA with AAA. Do NOT mix them when charging. However because they are rechargable batteries, you will want to keep an eye on the batteries incase they start to get warm.
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